Product ID:SODIUM FLUORIDE, (SEE SUPPLEMENTAL)
MSDS Date:01/16/1996
FSC:NIIN:Submitter:D DG
Status Code:A
MSDS Number: CKGCD

Emergency Phone: 716-226-6177

Info Phone: 1-419-589-1900

Preparer: MICHAEL RASZEJA

Cage: TO572

Telephone: 913-827-0451

Cage: 4A560

SODIUM FLUORIDE

CAS: 7681-49-4

RTECS: WB0350000

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:ORAL LD50(RAT): 64 MG/KG
Health Hazards Acute and Chronic:INHALATION: IRRITATING TO MUCOUS
MEMBRANES AND TOXIC WHEN INHALED. SKIN: MAY CAUSE DERMATITIS IF
EXPOSED TO DUST OR FUMES. EYES: CAUSES EYE IRRITATION. INGESTION:
SEVERE VOMITING, ABDOMINAL DISTRESS, DIARRHEA, STUPOR, WEAKNESS.
***POISON*** IF SWALLOWED OR INHALED.
Effects of Overexposure:INHALATION: CHILLS, LABORED BREATHING, FEVER,
UNPRODUCTIVE COUGH. INGESTION: SEVERE VOMITING, ABDOMINAL DISTRESS,
DIARRHEA, STUPOR AND WEAKNESS. POISON IF SWALLOWED OR INHALED.

First Aid:INHALATION:REMOVE FROM EXPOSURE, TREAT SYMPTOMATICALLY, GET
MEDICAL ATTENTION. EYES IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER
FOR AT LEAST 15 MINUTES, LIFTING LOWER & UPPER EYELIDS
OCCASIONALLY. GET PROMPT MEDICAL ATTENTION. SKIN:FLUSH SKIN WITH
PLENTY OF WATER. IF IRRITATION DEVELOPS, GET MEDICAL ATTENTION.
INGESTION:IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY GIVE SEVERAL
GLASSES OF MILK OR OTHER CALCIUM CONTAINING LIQUID IF AVAILABLE,
OTHERWISE GIVE LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.

Flash Point:NON-COMBUSTIBLE
Extinguishing Media:WATER FOG, DRY CHEMICAL (ABC), CARBON DIOXIDE.
Fire Fighting Procedures:IN FIRE CONDITIONS, WEAR A NIOSH/MSHA APPROVED
SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO
PREVENT CONTACT WITH SKIN AND EYES. DUST PRESENTS A RESPIRATORY AND
EYE HAZARD. MODERATELY WATER SOLUBLE.
Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS; CAN REACT VIGOROUSLY WITH ACID TO
LIBERATE CORROSIVE AND TOXIC HYDROGEN FLUORIDE. AVOID DUSTING
CONDITIONS. MAY FORM EXPLOSIVE DUST MIXTURES WITH AIR.

Spill Release Procedures:RECOVER FOR USE IF NOT CONTAMINATED. AVOID
INHALATION AND SKIN CONTACT. WEAR SUITABLE PROTECTIVE EQUIPMENT.
SWEEP UP AND PLACE IN SUITABLE CONTAINER FOR DISPOSAL, AVOID DUSTY
CONDITIONS. FLUSH SPILL A REA WITH SOAP AND WATER.

Handling and Storage Precautions:STORE IN COOL, DRY PLACE AWAY FROM
ACIDS AND ACID FUMES. WASH THOROUGHLY AFTER HANDLING. KEEP
CONTAINER TIGHTLY CLOSED WHEN NOT IN USE.
Other Precautions:AVOID INHALATION AND INGESTION. USE ADEQUATE
VENTILATION. AVOID CONTACT WITH SKIN OR EYES. REMOVE AND WASH
CONTAMINATED CLOTHING. FOR LABORATORY USE ONLY. KEEP OUT OF REACH
OF CHILDREN. NOT FOR DRU, F OOD OR HOUSEHOLD SUE. READ LABEL
BEFORE USING. DO NOT WEAR CONTACT LENSES WHEN WORKING WITH CHEMICA
LS.

Respiratory Protection:NONE NEEDED IN NORMAL LABORATORY HANDLING. IF
DUSTY CONDITIONS PREVAIL, WORK IN VENTILATION HOOD OR WEAR A
NIOSH/MSHA APPROVED ESPIRATOR.
Ventilation:LOCAL EXHAUST: YES. MECHANICAL: YES. OTHER: ADEQUATE TO
MAINTAIN BELOW EXPOSURE LIMIT.
Protective Gloves:RUBBER.
Eye Protection:CHEMICAL SAFETY GLASSES.
Other Protective Equipment:SMOCK, APRON, GOGGLES, VENTILATION HOOD,
PROPER GLOVES, EYE WASH STATION.
Work Hygienic Practices:REMOVE AND WASH CONTAMINATED CLOTHING.
Supplemental Safety and Health
****NOTE TO PHYSICIAN: FORMS HYDROFLUORIC ACID UPON CONTACT WITH ACID,
SUCH AS STOMACH ACID.**** 78521 SODIUM FLUORIDE-SCHOOL
SPECIALTY****

HCC:T3
Boiling Pt:=1704.C, 3099.2F
Melt/Freeze Pt:=993.C, ######F
Vapor Pres:1MM
Vapor Density:1.45
Spec Gravity:2.78 G/CC
Solubility in Water:4G/100G H20(0C)
Appearance and Odor:WHITE CRYSTALLINE POWDER; NO ODOR
Percent Volatiles by Volume:NEGLIGIBLE

Stability Indicator/Materials to Avoid:YES
ACIDS (REACTS WITH ACID TO FORM CORROSIVE AND TOXIC HYDROGEN FLUORIDE).
WATER FORMS SOLUTION CORROSIVE TO MANY MATERIALS, INCLUDING GLASS.
Stability Condition to Avoid:MOISTURE, EXTREME TEMPERATURE AND HEAT.
Hazardous Decomposition Products:HYDROGEN FLUORIDE. THE POSSIBILITY OF
TOXIC/HAZARDOUS FUMES OF FLUORINE AND SODIUM OXIDE SHOULD BE
CONSIDERED.

Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO FEDERAL, STATE OR LOCAL LAWS. THESE DISPOSAL GUIDE LINES ARE
INTENDED FOR CATALOG-SIZE QUANTITIES ONLY. DISPOSE OF CONTAINER AND
ANY RESIDUE ACCORDI NG TO LOCAL REGULATIONS.

Toxicological Information:TOXICITY DATA: ORL-RAT LD50 64 MG/KG,
ORL-HUMAN LDLO 75 MG/KG. OSHA/TWA: 2.5 MG/M3 (FLUORIDE AS F).

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Transport Information:D.O.T.: SODIUM FLUORIDE, 6.1, UN 1690.